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Jermain netted 15 times last season despite only making 17 starts and is sure to get more opportunities from the start this term.
£10 each-way would yield £135 if he comes second or third in the Golden Boot race.
14-goal Fredi Kanoute is 66/1 in the same market while Paolo Di Canio, who has scored 39 goals in 100 Premiership appearances for the club, can be backed at 80/1.
Kanoute/Defoe are 20/1 to score more goals combined than any other quoted Premiership strke partnership.
We are 200/1 to win the Premiership title, and although that might be out of reach, a £10 each-way title bet would return £410 if we finish in the top three and reach the Champions' League.
West Ham have been awarded 26 points on the Premiership handicap and we can be backed at 15/1 so it may be worth having a quid or two.
We kick-off our campaign at Newcastle and are 25/1 to score the quickest goal of the 20 top-flight clubs in the first weekend of action.
And 11/10 is the price if we collect in excess of 49 points.
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